Catalytic pyrolysis of crude glycerol over a shaped H-ZSM-5 zeolite catalyst with (partial) recycling of the product oil was studied with the incentive to improve benzene, toluene, and xylene (BTX) yields. Recycling of the polycyclic aromatic hydrocarbon (PAH) fraction, after separation from BTX by distillation and co-feeding with the crude glycerol feed, was shown to have a positive effect on the BTX yield. Further improvements were achieved by hydrogenation of the PAH fraction using a Ru/C catalyst and hydrogen gas prior to co-pyrolysis, and BTX yields up to 16 wt% on feed were obtained. The concept was also shown to be beneficial to other biomass feeds such as e.g., Kraft lignin, cellulose, and Jatropha oil.
Biogas plays an important role in many future renewable energy scenarios as a source of storable and easily extracted form of renewable energy. However, there remains uncertainty as to which sources of biomass can provide a net energy gain while being harvested in a sustainable, ecologically friendly manner. This study will focus on the utilization of common, naturally occurring grass species which are cut during landscape management and typically treated as a waste stream. This waste grass can be valorized through co-digestion with cow manure in a biogas production process. Through the construction of a biogas production model based on the methodology proposed by (Pierie, Moll, van Gemert, & Benders, 2012), a life cycle analysis (LCA) has been performed which determines the impacts and viability of using common grass in a digester to produce biogas. This model performs a material and energy flow analysis (MEFA) on the biogas production process and tracks several system indicators (or impact factors), including the process energy return on energy investment ((P)EROI), the ecological impact (measured in Eco Points), and the global warming potential (GWP, measured in terms of kg of CO2 equivalent). A case study was performed for the village of Hoogkerk in the north-east Netherlands, to determine the viability of producing a portion of the village’s energy requirements by biogas production using biomass waste streams (i.e. common grass and cow manure in a co-digestion process). This study concludes that biogas production from common grass can be an effective and sustainable source of energy, while reducing greenhouse gas emissions and negative environmental impacts when compared to alternate methods of energy production, such as biogas produced from maize and natural gas production.
Climate change calls for an energy transition utilizing all available renewable energy resources, such as bioenergy from biomass. However, the use of biomass is debated in society, and public acceptance is low or lacking. This survey-based research demonstrates for the first time that public acceptance of bioenergy hinges on (a) the type of biomass feedstock used to generate bioenergy and (b) the perceptions of the effectiveness of bioenergy in contributing to the energy transition. A survey-embedded vignette experiment (with 409 Dutch participants) shows that public acceptance of the biomass feedstocks 'wood' and 'energy crops' is significantly lower than the acceptance of 'organic waste' and 'manure' for bioenergy. These results indicate that the biomass feedstock type should be more carefully considered and specified in future research and communication on public acceptance of bioenergy. Thematic coding and bootstrapped mediation analyses identified the perceived effectivity of bioenergy in contributing to the energy transition as a prime explanatory (i.e., mediating) variable for acceptance. A subsequent message-framing communication experiment (with 414 Dutch participants) demonstrates that emphasizing biomass feedstock as a form of waste utilization is a frame that helps to increase public acceptance of bioenergy. The waste utilization frame notably improves the perceptions of the effectiveness of bioenergy as contributing to the energy transition for the two lesser accepted biomass feedstocks. The emphasis on biomass feedstock type as a form of waste treatment can improve strategic communications on bioenergy and foster wider public acceptance of bioenergy in the transition toward a more sustainable energy system.
In this proposal, a consortium of knowledge institutes (wo, hbo) and industry aims to carry out the chemical re/upcycling of polyamides and polyurethanes by means of an ammonolysis, a depolymerisation reaction using ammonia (NH3). The products obtained are then purified from impurities and by-products, and in the case of polyurethanes, the amines obtained are reused for resynthesis of the polymer. In the depolymerisation of polyamides, the purified amides are converted to the corresponding amines by (in situ) hydrogenation or a Hofmann rearrangement, thereby forming new sources of amine. Alternatively, the amides are hydrolysed toward the corresponding carboxylic acids and reused in the repolymerisation towards polyamides. The above cycles are particularly suitable for end-of-life plastic streams from sorting installations that are not suitable for mechanical/chemical recycling. Any loss of material is compensated for by synthesis of amines from (mixtures of) end-of-life plastics and biomass (organic waste streams) and from end-of-life polyesters (ammonolysis). The ammonia required for depolymerisation can be synthesised from green hydrogen (Haber-Bosch process).By closing carbon cycles (high carbon efficiency) and supplementing the amines needed for the chain from biomass and end-of-life plastics, a significant CO2 saving is achieved as well as reduction in material input and waste. The research will focus on a number of specific industrially relevant cases/chains and will result in economically, ecologically (including safety) and socially acceptable routes for recycling polyamides and polyurethanes. Commercialisation of the results obtained are foreseen by the companies involved (a.o. Teijin and Covestro). Furthermore, as our project will result in a wide variety of new and drop-in (di)amines from sustainable sources, it will increase the attractiveness to use these sustainable monomers for currently prepared and new polyamides and polyurethanes. Also other market applications (pharma, fine chemicals, coatings, electronics, etc.) are foreseen for the sustainable amines synthesized within our proposition.
By transitioning from a fossil-based economy to a circular and bio-based economy, the industry has an opportunity to reduce its overall CO2 emission. Necessary conditions for effective and significant reductions of CO2-emissions are that effective processing routes are developed that make the available carbon in the renewable sources accessible at an acceptable price and in process chains that produce valuable products that may replace fossil based products. To match the growing industrial carbon demand with sufficient carbon sources, all available circular, and renewable feedstock sources must be considered. A major challenge for greening chemistry is to find suitable sustainable carbon that is not fossil (petroleum, natural gas, coal), but also does not compete with the food or feed demand. Therefore, in this proposal, we omit the use of first generation substrates such as sugary crops (sugar beets), or starch-containing biomasses (maize, cereals).
In het project ‘AgroCycle’ wordt onderzocht of een coöperatie van boerderijen zelfvoorzienend kunnen worden in energie en bemesting door het gebruiken van mest in organische afvalstromen voor de productie van energie, groene brandstof en groene meststoffen door middel anaerobe vergisting. In het project beogen de projectpartners de nutriëntenkringloop (van mest tot digestaat tot groene meststof) te koppelen aan een zelfvoorzienend energiesysteem (biomassa tot biogas tot groene brandstof voor de bewerking van het land) door de gecombineerde productie van biogas en groene meststoffen. De financiële haalbaarheid van een biovergister is sterk afhankelijk van het gebruik en de economische waarde van het digestaat. Met deze gecombineerde aanpak wordt zowel de haalbaarheid als de duurzaamheid (milieueffecten en CO2 - emissies) vergroot. Om de haalbaarheid van dit concept te onderzoeken wordt gebruik gemaakt van het bestaande model ‘BioGas simulator’ dat door de Hanzehogeschool Groningen ontwikkeld is om het technische proces van decentrale productie van biogas te kunnen simuleren.
