The improvement of passive fire protection of storage vessels is a key factor to enhance safety among the LPG distribution chain. A thermal and mechanical model based on finite elements simulations was developed to assess the behaviour of full size tanks used for LPG storage and transportation in fire engulfment scenarios. The model was validated by experimental results. A specific analysis of the performance of four different reference coating materials was then carried out, also defining specific key performance indicators (KPIs) to assess design safety margins in near-miss simulations. The results confirmed the wide influence of coating application on the expected vessel time to failure due to fire engulfment. Aquite different performance of the alternative coating materialswas evidenced. General correlationswere developed among the vessel time to failure and the effective coating thickness in full engulfment scenarios, providing a preliminary assessment of the coating thickness required to prevent tank rupture for a given time lapse. The KPIs defined allowed the assessment of the available safety margins in the reference scenarios analyzed and of the robustness of thermal protection design.
MULTIFILE
From the article: Abstract Sub-chronic toxicity studies of 163 non-genotoxic chemicals were evaluated in order to predict the tumour outcome of 24-month rat carcinogenicity studies obtained from the EFSA and ToxRef databases. Hundred eleven of the 148 chemicals that did not induce putative preneoplastic lesions in the sub-chronic study also did not induce tumours in the carcinogenicity study (True Negatives). Cellular hypertrophy appeared to be an unreliable predictor of carcinogenicity. The negative predictivity, the measure of the compounds evaluated that did not show any putative preneoplastic lesion in de sub-chronic studies and were negative in the carcinogenicity studies, was 75%, whereas the sensitivity, a measure of the sub-chronic study to predict a positive carcinogenicity outcome was only 5%. The specificity, the accuracy of the sub-chronic study to correctly identify non-carcinogens was 90%. When the chemicals which induced tumours generally considered not relevant for humans (33 out of 37 False Negatives) are classified as True Negatives, the negative predictivity amounts to 97%. Overall, the results of this retrospective study support the concept that chemicals showing no histopathological risk factors for neoplasia in a sub-chronic study in rats may be considered non-carcinogenic and do not require further testing in a carcinogenicity study.
Wind and solar power generation will continue to grow in the energy supply of the future, but its inherent variability (intermittency) requires appropriate energy systems for storing and using power. Storage of possibly temporary excess of power as methane from hydrogen gas and carbon dioxide is a promising option. With electrolysis hydrogen gas can be generated from (renewable) power. The combination of such hydrogen with carbon dioxide results in the energy carrier methane that can be handled well and may may serve as carbon feedstock of the future. Biogas from biomass delivers both methane and carbon dioxide. Anaerobic microorganisms can make additional methane from hydrogen and carbon dioxide in a biomethanation process that compares favourably with its chemical counterpart. Biomethanation for renewable power storage and use makes appropriate use of the existing infrastructure and knowledge base for natural gas. Addition of hydrogen to a dedicated biogas reactor after fermentation optimizes the biomethanation conditions and gives maximum flexibility. The low water solubility of hydrogen gas limits the methane production rate. The use of hollow fibers, nano-bubbles or better-tailored methane-forming microorganisms may overcome this bottleneck. Analyses of patent applications on biomethanation suggest a lot of freedom to operate. Assessment of biomethanation for economic feasibility and environmental value is extremely challenging and will require future data and experiences. Currently biomethanation is not yet economically feasible, but this may be different in the energy systems of the near future.
Carbon dioxide (CO2) is the final waste product for all carbon-containing products. Its reuse will partly mitigate climate change and, in addition, provide a valuable feedstock for fuels and chemicals. Zuyd University of Applied Sciences (ZUYD), Innosyn B.V., and Chemtrix B.V. will develop a flow reactor for photochemical reactions with gases conducted at high pressure. This reactor is the necessary first development towards artificial photosynthesis: the connection of hydrogen (H2) to the ultimate waste product CO2 to store energy in a chemical bond, in order to produce so-called solar fuels and C1-chemicals/products. With an increasing amount of renewables in the energy system, energy storage becomes increasingly important to continuously match supply and demand. In a cooperation between three ZUYD research groups with Chemtrix B.V. and Innosyn B.V., multiple cost-efficient reactor designs for this flow reactor will be analyzed and two designs will be selected to be implemented by small extensions of existing equipment. Simultaneously, two appropriate test re-actions involving a gas (E-Z isomerization followed by hydrogenation) and with a CO2 analogue (a hydrogenation of a carboxylic acid) will be developed to be conducted in the reactor when the con-struction has been finished. We aim to disseminate the new capabilities developed in this KIEM proposal by the project partners with respect to the new reactors to several selected stakeholders. Furthermore, to expand the project several options (SIA-RAAK and H2020 grants) will be explored.
Surface Active Agents, or surfactants, are chemicals which provide a surface (interface) activity when dispersed in liquids. They have different purposes, can be used as herbicides, anti-foaming agents, adhesives, cleaning agents and softeners. For cleaning purposes, their function is to alter (decrease) liquid surface tension. In this function they are ubiquitous in both industrial processes (cleaning of production equipment, storage vats, packaging lines, and cooking units either during the manufacturing process) and domestic applications. ProtoNeat proposes an alternative way to decrease water surface tension without adding chemicals (surfactants). This can be done by charging the water (producing protonically charged water) [2], i.e. positive and negative Bjerrum-defect like charges [3, 4]. This phenomenon was experimentally observed by Fuchs et al [5] in anolyte and catholyte when doing high voltage electrolysis of highly pure water during the so-called ‘floating water bridge’ experiment. The work done by the authors, when working with this “bridge”, showed that, in case of positive excess charge, the hydronium ions migrate to the surface [8] thereby significantly lowering the surface tension [9,10]. However, for how long this effect can be maintained and how effective it is to produce such water is still unknown. ProtoNeat wants to tackle these two questions and investigate whether a continuous production of protonically charged water as an environmentally friendly and sustainable cleaning agent is possible.
Thermal batteries, which store and release energy by hydrating and dehydrating salt crystals, hold great promise for domestic heating. Such batteries can be charged from waste heat from industrial processes, and discharged to provide neighbourhood heating. Unlike hot water storage systems, the energy is stored at room temperature, so the thermal losses are very low, making a salt battery highly efficient. However, the electrochemical change of the salt due to hydration and dehydration is very small, making it difficult to measure how much energy is stored in a battery. One promising technique is to measure the absolute humidity of the inlet and outlet air flow. The difference in humidity, combined with a rate equation model allows the total mass of water stored in the battery to be calculated, which can then be used to calculate the energy storage and battery power flow. However, there are several uncertainties in this approach. Commercially available sensors age over time, sometimes quite suddenly. It is not yet known if software can be used to compensate for sensor aging, or if a different sensor type is required. In addition to aging, each measurement is subject to random noise, which will be integrated into the model used to calculate the charge of the battery. It is not yet known how the noise will influence charge estimates. On the other hand, the sensor system must be as durable as domestic heating systems (decades). Hence, it is required to understand sensor aging in order to validate the sensor system for its intended use.