Designing lead-free piezoelectric ceramics with tailored electrical properties remains a critical challenge for various applications. In this paper we present a novel methodology integrating Machine Learning (ML) and optimization procedures to fine-tune electrical properties in lead-free (1-x) Na0.5 Bi0.5 TiO3 - x CaTiO3 piezoelectric ceramics. A comprehensive dataset of dielectric measurements serves as the foundation for training ML models that accurately predict the permittivity (𝜀′) and dielectric loss (tan 𝛿) as functions of Ca2+concentration (x % Ca), temperature and frequency. Two ML techniques are evaluated: random forest regression, and Multi-Layer Perceptron neural network Regression (MLPR). The MLPR model exhibited a superior regression performance, achieving a correlation coefficient of 0.931 and a root mean squared error of 0.029. The MLPR was then optimized by the Non-dominated Sorting Genetic Algorithm II (NSGA-II) to maximizes 𝜀′ while minimizes tan 𝛿. Within the NSGA-II framework, the optimal values were found at the Pareto curve knee, corresponding to a frequency, temperature, and x % Ca of 609.739 kHz, 398.15 K, and 6.10, respectively, resulting in 𝜀′ equal to 857.87 and tan 𝛿 equal to 0.0120. This approach demonstrates the effectiveness of combining ML andoptimization for designing the electrical properties of piezoelectric ceramics, paving the way for more efficient and targeted material development.
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With a market demand for low cost, easy to produce, flexible and portable applications in healthcare, energy, biomedical or electronics markets, large research programs are initiated to develop new technologies to provide this demand with new innovative ideas. One of these fast developing technologies is organic printed electronics. As the term printed electronics implies, functional materials are printed via, e.g. inkjet, flexo or gravure printing techniques, on to a substrate material. Applications are, among others, organic light emitting diodes (OLED), sensors and Lab-on-a-chip devices. For all these applications, in some way, the interaction of fluids with the substrate is of great importance. The most used substrate materials for these low-cost devices are (coated) paper or plastic. Plastic substrates have a relatively low surface energy which frequently leads to poor wetting and/or poor adhesion of the fluids on the substrates during printing and/ or post-processing. Plasma technology has had a long history in treating materials in order to improve wetting or promote adhesion. The µPlasma patterning tool described in this thesis combines a digital inkjet printing platform with an atmospheric dielectric barrier discharge plasma tool. Thus enabling selective and local plasma treatment, at atmospheric pressure, of substrates without the use of any masking materials. In this thesis, we show that dependent on the gas composition the substrate surface can either be functionalized, thus increasing its surface energy, or material can be deposited on the surface, lowering its surface energy. Through XPS and ATR-FTIR analysis of the treated (polymer) substrate surfaces, chemical modification of the surface structure was confirmed. The chemical modification and wetting properties of the treated substrates remained present for at least one month after storage. Localized changes in wettability through µPlasma patterning were obtained with a resolution of 300µm. Next to the control of wettability of an ink on a substrate in printed electronics is the interaction of ink droplets with themselves of importance. In printing applications, coalescence of droplets is standard practice as consecutive droplets are printed onto, or close to each other. Understanding the behaviour of these droplets upon coalescence is therefore important, especially when the ink droplets are of different composition and/or volume. For droplets of equal volume, it was found that dye transport across the coalescence bridge could be fully described by diffusion only. This is as expected, as due to the droplet symmetry on either side of the bridge, the convective flows towards the bridge are of equal size but opposite in direction. For droplets of unequal volume, the symmetry across the bridge is no longer present. Experimental analysis of these merging droplets show that in the early stages of coalescence a convective flow from the small to large droplet is present. Also, a smaller convective flow of shorter duration from the large into the small droplet was identified. The origin of this flow might be due to the presence of vortices along the interface of the bridge, due to the strong transverse flow to open the bridge. To conclude, three potential applications were showcased. In the first application we used µPlasma patterning to create hydrophilic patterns on hydrophobic dodecyl-trichlorosilane (DTS) covered glass. Capillaries for a Lab-on-a-chip device were successfully created by placing two µPlasma patterned glass slides on top of each other separated by scotch tape. In the second application we showcased the production of a RFID tag via inkjet printing. Functional RFID-tags on paper were created via inkjet printing of silver nanoparticle ink connected to an integrated circuit. The optimal operating frequency of the produced tags is in the range of 860-865 MHz, making them usable for the European market, although the small working range of 1 m needs further improvement. Lastly, we showed the production of a chemresistor based gas sensor. In house synthesised polyemeraldine salt (PANi) was coated by hand on top of inkjet printed silver electrodes. The sensor proved to be equally sensitive to ethanol and water vapour, reducing its selectivity in detecting changes in gas composition.
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İnsan vücudu ile elektromanyetik dalgaların etkileşimi, dokuların ve hücrelerin dielektrik özellikleri gibi faktörlerin yanı sıra diğer etkenler tarafından da şekillenir. Mikrodalga hipertermi ve mikrodalga görüntüleme uygulamalarında, deney ortamı ölçüm düzeneklerinde simülasyon sonuçlarını doğrulamak için doku taklit eden materyallere ihtiyaç vardır. Bu çalışmada hipertermi uygulamalarında kullanılmak üzere kadın memelerine ait bazı doku taklit materyallerinin karakterizasyonu sunulmuştur. Karakterize edilen doku taklit malzemelerinin maliyeti ucuz ve üretim aşamaları kolaydır. Deri, kas, meme yağı ve kanserli dokular ISM bandı 434 MHz'de önerilmektedir. The interaction of electromagnetic waves with the human body is determined by the dielectric properties of tissues and cells along with other considerations. The complex dielectric properties of the materials are very important for the interaction of the electromagnetic waves within the human body. In microwave hyperthermia and microwave imaging applications, there is a need of tissue mimicking materials to validate the simulation results in in vitro measurement setups. In this paper, we presented the characterization of some tissue materials belonging to female breast to be used for hyperthermia applications. The characterized tissue mimicking materials are inexpensive and have simple recipes that are easy to formulate. Skin, muscle, breast fat and cancerous tissues are proposed at ISM band 434 MHz.
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