One of the issues concerning the replacement of natural gas by green gas is the seasonal pattern of the gas demand. When constant production is assumed, this may limit the injected quantity of green gas into a gas grid to the level of the minimum gas demand in summer. A procedure was proposed to increase thegas demand coverage in a geographical region, i.e., the extent to which natural gas demand is replaced by green gas. This was done by modeling flexibility into farm-scale green gas supply chains. The procedure comprises two steps. In the first step, the types and number of green gas production units are determined,based on a desired gas demand coverage. The production types comprise time-varying biogas production, non-continuous biogas production (only in winter periods with each digester having a specified production time) and constant production including seasonal gas storage. In the second step locations of production units and injection stations are calculated, using mixed integer linear programming with cost price minimization being the objective. Five scenarios were defined with increasing gas demand coverage, representing a possible future development in natural gas replacement. The results show that production locations differ for each scenario, but are connected to a selection of injection stations, at least in the considered geographical region under the assumed preconditions. The cost price is mainly determined by the type of digesters needed. Increasing gas demand coverage does not necessarily mean a much higher cost price.
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From the article: "A facile approach for the fabrication of large-scale interdigitated nanogap electrodes (nanogap IDEs) with a controllable gap was demonstrated with conventional micro-fabrication technology to develop chemocapacitors for gas sensing applications. In this work, interdigitated nanogap electrodes (nanogap IDEs) with gaps from 50–250 nm have been designed and processed at full wafer-scale. These nanogap IDEs were then coated with poly(4-vinyl phenol) as a sensitive layer to form gas sensors for acetone detection at low concentrations. These acetone sensors showed excellent sensing performance with a dynamic range from 1000 ppm to 10 ppm of acetone at room temperature and the observed results are compared with conventional interdigitated microelectrodes according to our previous work. Sensitivity and reproducibility of devices are discussed in detail. Our approach of fabrication of nanogap IDEs together with a simple coating method to apply the sensing layer opens up possibilities to create various nanogap devices in a cost-effective manner for gas sensing applications"
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Post-earthquake structural damage shows that out-of-plane wall collapse is one of the most prevalent failure mechanisms in unreinforced masonry (URM) buildings. This issue is particularly critical in Groningen, a province located in the northern part of the Netherlands, where low-intensity ground shaking has occurred since 1991 due to gas extraction. The majority of buildings in this area are constructed using URM and were not designed to withstand earthquakes, as the area had never been affected by tectonic seismic activity before. Hence, the assessment of URM buildings in the Groningen province has become of high relevance.Out-of-plane failure mechanisms in brick masonry structures often stem from poor wall-to-wall, wall-to-floor or wall-to-roof connections that provide insufficient restraint and boundary conditions. Therefore, studying the mechanical behaviour of such connections is of prime importance for understanding and preventing damages and collapses in URM structures. Specifically, buildings with double-leaf cavity walls constitute a large portion of the building stock in the Groningen area. The connections of the leaves in cavity walls, which consist of metallic ties, are expected to play an important role. Regarding the wall-to-floor connections, the traditional way for URM structures in Dutch construction practice is either a simple masonry pocket connection or a hook anchor as-built connection, which are expected to be vulnerable to out-of-plane excitation. However, until now, little research has been carried out to characterise the seismic behaviour of connections between structural elements in traditional Dutch construction practice.This thesis investigates the seismic behaviour of two types of connections: wall-to-wall connections between cavity wall leaves and wall-to-floor connections between the masonry cavity wall and timber diaphragm, commonly found in traditional houses in the Groningen area. The research is divided into three phases: (1) inventory of existing buildings and connections in the Groningen area, (2) performance of experimental tests, and (3) proposal and validation of numerical and mechanical models. The thesis explores the three phases as follows:(i) An inventory of connections within URM buildings in the Groningen area is established. The inventory includes URM buildings of Groningen based on construction material, lateral load-resisting system, floor system, number of storeys, and connection details. Specific focus is given to the wall-to-wall and wall-to-floor connections in each URM building. The thickness of cavity wall leaves, the air gap between the leaves and the size and spacing of timber joists are key aspects of the inventory.(ii) Experimental tests are performed on the most common connection typologies identified in the inventory. This phase consists of two distinct experimental campaigns:o The first experimental campaign took place at the laboratory of the Delft University of Technology to provide a comprehensive characterisation of the axial behaviour of traditional metal tie connections in cavity walls. The campaign included a wide range of variations, such as two embedment lengths, four pre-compression levels, two different tie geometries, and five different testing protocols, including both monotonic and cyclic loading. The experimental results showed that the capacity of the wall tie connection is strongly influenced by the embedment length and the tie geometry, whereas the applied pre-compression and the loading rate do not have a significant influence.o The second experimental campaign has been carried out at the laboratory of the Hanze University of Applied Sciences to characterise the seismic behaviour of timber joist-masonry cavity wall connections, reproducing both as-built and strengthened conditions. Twenty-two unreinforced masonry wallets were tested, with different configurations, including two tie distributions, two pre-compression levels, two different as-built connections, and two different strengthening solutions. The experimental results highlighted the importance of cohesion and friction between joist and masonry since the type of failure mechanism (sliding of the joist or rocking failure of the masonry wallet) depends on the value of these two parameters. Additionally, the interaction between the joist and the wallet and the uplift of the latter activated due to rocking led to an arching effect that increased friction at the interface between the joist and the masonry. Consequently, the arching effect enhanced the force capacity of the connection.(iii) Mechanical and numerical models are proposed and validated against the performed experiments or other benchmarks. Mechanical and numerical models for the cavity wall tie and mechanical models for the timber joist-masonry connections were developed and verified by the experimental results to predict the failure mode and the strength capacity of the examined connections in URM buildings.o The mechanical model for the cavity wall tie connections considers six possible failures, namely tie failure, cone break-out failure, pull-out failure, buckling failure, piercing failure and punching failure. The mechanical model is able to capture the mean peak force and the failure mode obtained from the tests. After being calibrated against the available experiments, the proposed mechanical model is used to predict the performance of untested configurations by means of parametric analyses, including higher strength of mortar for calcium silicate brick masonry, different cavity depth, different tie embedment depth, and the use of solid bricks in place of perforated clay bricks.o The results of the experimental campaign on cavity wall ties were also utilised to calibrate a hysteretic numerical model representing the cyclic axial response of cavity wall tie connections. The proposed model uses zero-length elements implemented in OpenSees with the Pinching4 constitutive model to account for the compression-tension cyclic behaviour of the ties. The numerical model is able to capture important aspects of the tie response, such as strength degradation, unloading stiffness degradation, and pinching behaviour. The mechanical and numerical modelling approach can be easily adopted by practitioner engineers seeking to model the wall ties more accurately when assessing URM structures against earthquakes.o The mechanical model of timber-masonry connections examines two different failure modes: joist-sliding failure mode, including joist-to-wall interaction and rocking failure mode due to joist movement. Both mechanical models have been validated against the outcomes of the experimental campaigns conducted on the corresponding connections. The mechanical model is able to estimate each contribution of the studied mechanism. Structural engineers can use the mechanical model to predict the capacity of the connection for the studied failure modes.This research study can contribute to a better understanding of typical Groningen houses in terms of identifying the most common connections used at wall-to-wall and wall-to-floor connections in cavity walls, characterising the identified connections and proposing mechanical models for the studied connections.
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The production of biogas through anaerobic digestion is one of the technological solutions to convert biomass into a readily usable fuel. Biogas can replace natural gas, if the biogas is upgraded to green gas. To contribute to the EU-target to reduce Green House Gases emissions, the installed biogas production capacity and the amount of farm-based biomass, as a feedstock, has to be increased. A model was developed to describe a green gas production chain that consists of several digesters connected by a biogas grid to anupgrading and injection facility. The model calculates costs and energy use for 1 m3 of green gas. The number of digesters in the chain can be varied to find results for different configurations. Results are presented for a chain with decentralized production of biogas, i.e. a configuration with several digesters, and a centralized green gas production chain using a single digester. The model showed that no energy advantage per produced m3 green gas can be created using a biogas grid and decentralized digesters instead of one large-scale digester. Production costs using a centralized digester are lower, in the range of5 Vct to 13 Vct per m3, than in a configuration of decentralized digesters. The model calculations also showed the financial benefit for an operator of a small-scale digester wishing to produce green gas in the cooperation with nearby other producers. E.g. subsidies and legislation based on environmental arguments could encourage the use of decentralized digesters in a biogas grid.
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In de afgelopen twee jaar is veel veranderd op juridisch vlak als het gaat om de rechtspositie van de consument en diens aansluiting op het aardgassysteem. In deze bijdrage verkennen we de juridische mogelijkheden én onmogelijkheden van twee uitgangsposities: a. die van de burger die graag zelf actie wil ondernemen om van het gas af te gaan en b. die van de gasklever, oftewel de burger die wil vasthouden aan het gas omdat hij geen heil ziet in de energietransitie, de alternatieve voorziening geen verbetering of te duur is, diens huis niet geschikt is voor een warmtepomp of omdat hij de woning volledig op elektriciteit wil. In dit laatste geval wordt vervolgens uiteengezet in hoeverre de gastrouwe burger gedwongen kan worden onder huidig en toekomstig recht toch de overstap te maken naar een energievoorziening zonder aardgas. Voor de uiteenzetting van deze uitgangsposities wordt kort de achtergrond van de warmtetransitie geschetst en de manier waarop deze via de transitievisie warmte, met de gemeente aan kop, tot stand moet gaan komen. Het Wetsvoorstel gemeentelijke instrumenten warmtetransitie wordt hier tevens besproken.
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The period leading to and immediately after the release of the IPCC's fifth series of climate change assessments saw substantial efforts by climate change denial interests to portray anthropogenic climate change (ACC) as either unproven theory or a negligible contribution to natural climate variability, including the relationship between tourism and climate change. This paper responds to those claims by stressing that the extent of scientific consensus suggests that human-induced warming of the climate system is unequivocal. Second, it responds in the context of tourism research and ACC, highlighting tourism's significant contribution to greenhouse gas emissions, as well as climate change's potential impacts on tourism at different scales. The paper exposes the tactics used in ACC denial papers to question climate change science by referring to non-peer-reviewed literature, outlier studies, and misinterpretation of research, as well as potential links to think tanks and interest groups. The paper concludes that climate change science does need to improve its communication strategies but that the world-view of some individuals and interests likely precludes acceptance. The connection between ACC and sustainability illustrates the need for debate on adaptation and mitigation strategies, but that debate needs to be grounded in scientific principles not unsupported skepticism.
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Validity and Reproducibility of a New Treadmill Protocol: The Fitkids Treadmill Test. Med. Sci. Sports Exerc., Vol. 47, No. 10, pp. 2241–2247, 2015. Purpose: This study aimed to investigate the validity and reproducibility of a new treadmill protocol in healthy children and adolescents: the Fitkids Treadmill Test (FTT). Methods: Sixty-eight healthy children and adolescents (6–18 yr) were randomly divided into a validity group (14 boys and 20 girls; mean T SD age, 12.9 T 3.6 yr) that performed the FTT and Bruce protocol, both with respiratory gas analysis within 2 wk, and a reproducibility group (19 boys and 15 girls; mean T SD age, 13.5 T 3.5 yr) that performed the FTT twice within 2 wk. A subgroup of 21 participants within the reproducibility group performed both FTT with respiratory gas analysis. Time to exhaustion (TTE) was the main outcome of the FTT. Results: V˙ O2peak measured during the FTT showed excellent correlation with V˙ O2peak measured during the Bruce protocol (r = 0.90; P G 0.01). Backward multiple regression analysis provided the following prediction equations for V˙ O2peak (LIminj1) for boys and girls, respectively: V˙ O2peak FTT ¼ j0:748 þ ð0:117 TTEFTTÞ þ ð0:032 bodymassÞ þ 0:263, and V˙ O2peak FTT ¼ j0:748 þ ð0:117 TTEFTTÞ þ ð0:032 bodymassÞ [R2 ¼ 0:935; SEE ¼ 0:256LI min j1]. Cross-validation of the regression model showed an R2 value of 0.76. Reliability statistics for the FTT showed an intraclass correlation coefficient of 0.985 (95% confidence interval, 0.971–0.993; P G 0.001) for TTE. Bland–Altman analysis showed a mean bias of j0.07 min, with limits of agreement between +1.30 and j1.43 min. Conclusions: Results suggest that the FTT is a useful treadmill protocol with good validity and reproducibility in healthy children and adolescents. Exercise performance on the FTT and body mass can be used to adequately predict V˙ O2peak when respiratory gas analysis is not available.
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The context of a societal challenge provides insight into the complexity of the (eco-)system surrounding the current problematic situation: the environment, the stakeholders (including nature), the highlights and frustrations, the conflicts and dilemmas, and the opportunities for change. Why is this co-design session arranged? What problematic situation is encountered? Who (individual or group) took the initiative to act? Is there a specific reason to collaboratively start taking up this societal challenge? Does everyone in this session recognise the problematic situation? Why or why not?
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With a market demand for low cost, easy to produce, flexible and portable applications in healthcare, energy, biomedical or electronics markets, large research programs are initiated to develop new technologies to provide this demand with new innovative ideas. One of these fast developing technologies is organic printed electronics. As the term printed electronics implies, functional materials are printed via, e.g. inkjet, flexo or gravure printing techniques, on to a substrate material. Applications are, among others, organic light emitting diodes (OLED), sensors and Lab-on-a-chip devices. For all these applications, in some way, the interaction of fluids with the substrate is of great importance. The most used substrate materials for these low-cost devices are (coated) paper or plastic. Plastic substrates have a relatively low surface energy which frequently leads to poor wetting and/or poor adhesion of the fluids on the substrates during printing and/ or post-processing. Plasma technology has had a long history in treating materials in order to improve wetting or promote adhesion. The µPlasma patterning tool described in this thesis combines a digital inkjet printing platform with an atmospheric dielectric barrier discharge plasma tool. Thus enabling selective and local plasma treatment, at atmospheric pressure, of substrates without the use of any masking materials. In this thesis, we show that dependent on the gas composition the substrate surface can either be functionalized, thus increasing its surface energy, or material can be deposited on the surface, lowering its surface energy. Through XPS and ATR-FTIR analysis of the treated (polymer) substrate surfaces, chemical modification of the surface structure was confirmed. The chemical modification and wetting properties of the treated substrates remained present for at least one month after storage. Localized changes in wettability through µPlasma patterning were obtained with a resolution of 300µm. Next to the control of wettability of an ink on a substrate in printed electronics is the interaction of ink droplets with themselves of importance. In printing applications, coalescence of droplets is standard practice as consecutive droplets are printed onto, or close to each other. Understanding the behaviour of these droplets upon coalescence is therefore important, especially when the ink droplets are of different composition and/or volume. For droplets of equal volume, it was found that dye transport across the coalescence bridge could be fully described by diffusion only. This is as expected, as due to the droplet symmetry on either side of the bridge, the convective flows towards the bridge are of equal size but opposite in direction. For droplets of unequal volume, the symmetry across the bridge is no longer present. Experimental analysis of these merging droplets show that in the early stages of coalescence a convective flow from the small to large droplet is present. Also, a smaller convective flow of shorter duration from the large into the small droplet was identified. The origin of this flow might be due to the presence of vortices along the interface of the bridge, due to the strong transverse flow to open the bridge. To conclude, three potential applications were showcased. In the first application we used µPlasma patterning to create hydrophilic patterns on hydrophobic dodecyl-trichlorosilane (DTS) covered glass. Capillaries for a Lab-on-a-chip device were successfully created by placing two µPlasma patterned glass slides on top of each other separated by scotch tape. In the second application we showcased the production of a RFID tag via inkjet printing. Functional RFID-tags on paper were created via inkjet printing of silver nanoparticle ink connected to an integrated circuit. The optimal operating frequency of the produced tags is in the range of 860-865 MHz, making them usable for the European market, although the small working range of 1 m needs further improvement. Lastly, we showed the production of a chemresistor based gas sensor. In house synthesised polyemeraldine salt (PANi) was coated by hand on top of inkjet printed silver electrodes. The sensor proved to be equally sensitive to ethanol and water vapour, reducing its selectivity in detecting changes in gas composition.
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In recent years, the number of human-induced earthquakes in Groningen, a large gas field in the north of the Netherlands, has increased. The majority of the buildings are built by using unreinforced masonry (URM), most of which consists of cavity (i.e. two-leaf) walls, and were not designed to withstand earthquakes. Efforts to define, test and standardize the metal ties, which do play an important role, are valuable also from the wider construction industry point of view. The presented study exhibits findings on the behavior of the metal tie connections between the masonry leaves often used in Dutch construction practice, but also elsewhere around the world. An experimental campaign has been carried out at Delft University of Technology to provide a complete characterization of the axial behavior of traditional connections in cavity walls. A large number of variations was considered in this research: two embedment lengths, four pre-compression levels, two different tie geometries, and five different testing protocols, including monotonic and cyclic loading. The experimental results showed that the capacity of the connection was strongly influenced by the embedment length and the geometry of the tie, whereas the applied pre-compression and the loading rate did not have a significant influence.
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