From the article: "A facile approach for the fabrication of large-scale interdigitated nanogap electrodes (nanogap IDEs) with a controllable gap was demonstrated with conventional micro-fabrication technology to develop chemocapacitors for gas sensing applications. In this work, interdigitated nanogap electrodes (nanogap IDEs) with gaps from 50–250 nm have been designed and processed at full wafer-scale. These nanogap IDEs were then coated with poly(4-vinyl phenol) as a sensitive layer to form gas sensors for acetone detection at low concentrations. These acetone sensors showed excellent sensing performance with a dynamic range from 1000 ppm to 10 ppm of acetone at room temperature and the observed results are compared with conventional interdigitated microelectrodes according to our previous work. Sensitivity and reproducibility of devices are discussed in detail. Our approach of fabrication of nanogap IDEs together with a simple coating method to apply the sensing layer opens up possibilities to create various nanogap devices in a cost-effective manner for gas sensing applications"
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Wind and solar power generation will continue to grow in the energy supply of the future, but its inherent variability (intermittency) requires appropriate energy systems for storing and using power. Storage of possibly temporary excess of power as methane from hydrogen gas and carbon dioxide is a promising option. With electrolysis hydrogen gas can be generated from (renewable) power. The combination of such hydrogen with carbon dioxide results in the energy carrier methane that can be handled well and may may serve as carbon feedstock of the future. Biogas from biomass delivers both methane and carbon dioxide. Anaerobic microorganisms can make additional methane from hydrogen and carbon dioxide in a biomethanation process that compares favourably with its chemical counterpart. Biomethanation for renewable power storage and use makes appropriate use of the existing infrastructure and knowledge base for natural gas. Addition of hydrogen to a dedicated biogas reactor after fermentation optimizes the biomethanation conditions and gives maximum flexibility. The low water solubility of hydrogen gas limits the methane production rate. The use of hollow fibers, nano-bubbles or better-tailored methane-forming microorganisms may overcome this bottleneck. Analyses of patent applications on biomethanation suggest a lot of freedom to operate. Assessment of biomethanation for economic feasibility and environmental value is extremely challenging and will require future data and experiences. Currently biomethanation is not yet economically feasible, but this may be different in the energy systems of the near future.
From Springer description: "We present the design considerations of an autonomous wireless sensor and discuss the fabrication and testing of the various components including the energy harvester, the active sensing devices and the power management and sensor interface circuits. A common materials platform, namely, nanowires, enables us to fabricate state-of-the-art components at reduced volume and show chemical sensing within the available energy budget. We demonstrate a photovoltaic mini-module made of silicon nanowire solar cells, each of 0.5 mm2 area, which delivers a power of 260 μW and an open circuit voltage of 2 V at one sun illumination. Using nanowire platforms two sensing applications are presented. Combining functionalised suspended Si nanowires with a novel microfluidic fluid delivery system, fully integrated microfluidic–sensor devices are examined as sensors for streptavidin and pH, whereas, using a microchip modified with Pd nanowires provides a power efficient and fast early hydrogen gas detection method. Finally, an ultra-low power, efficient solar energy harvesting and sensing microsystem augmented with a 6 mAh rechargeable battery allows for less than 20 μW power consumption and 425 h sensor operation even without energy harvesting."
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In this proposal, a consortium of knowledge institutes (wo, hbo) and industry aims to carry out the chemical re/upcycling of polyamides and polyurethanes by means of an ammonolysis, a depolymerisation reaction using ammonia (NH3). The products obtained are then purified from impurities and by-products, and in the case of polyurethanes, the amines obtained are reused for resynthesis of the polymer. In the depolymerisation of polyamides, the purified amides are converted to the corresponding amines by (in situ) hydrogenation or a Hofmann rearrangement, thereby forming new sources of amine. Alternatively, the amides are hydrolysed toward the corresponding carboxylic acids and reused in the repolymerisation towards polyamides. The above cycles are particularly suitable for end-of-life plastic streams from sorting installations that are not suitable for mechanical/chemical recycling. Any loss of material is compensated for by synthesis of amines from (mixtures of) end-of-life plastics and biomass (organic waste streams) and from end-of-life polyesters (ammonolysis). The ammonia required for depolymerisation can be synthesised from green hydrogen (Haber-Bosch process).By closing carbon cycles (high carbon efficiency) and supplementing the amines needed for the chain from biomass and end-of-life plastics, a significant CO2 saving is achieved as well as reduction in material input and waste. The research will focus on a number of specific industrially relevant cases/chains and will result in economically, ecologically (including safety) and socially acceptable routes for recycling polyamides and polyurethanes. Commercialisation of the results obtained are foreseen by the companies involved (a.o. Teijin and Covestro). Furthermore, as our project will result in a wide variety of new and drop-in (di)amines from sustainable sources, it will increase the attractiveness to use these sustainable monomers for currently prepared and new polyamides and polyurethanes. Also other market applications (pharma, fine chemicals, coatings, electronics, etc.) are foreseen for the sustainable amines synthesized within our proposition.
Belangrijke uitdagingen binnen de energietransitie zijn de beschikbaarheid van waterstof uit duurzame energiebronnen als alternatief voor fossiele brandstoffen en het voorkomen van congestie op het elektriciteitsnet door toenemende vraag naar en aanbod van elektriciteit. Decentrale productie, opslag en toepassing van waterstof biedt voor beide uitdagingen een oplossing, maar om dit te realiseren zijn innovaties en kennisontwikkeling nodig. In dit RAAK MKB project willen bedrijven en kennisinstellingen als partners van het groeiende netwerk rondom waterstof innovatiecentrum H2Hub Twente, expertise ontwikkelen voor realisatie van decentrale elektrolyse systemen. De betrokken bedrijven zijn zich aan het ontwikkelen om systeemoplossingen voor de markt van decentrale elektrolyse aan te kunnen bieden, maar hebben nog stappen te maken in de benodigde expertise hiervoor. De kloof die de bedrijven in dit project willen overbruggen: van theoretisch inzicht en expertise op deelaspecten naar expertise om goed werkende systemen te kunnen realiseren en begrip krijgen van mogelijkheden voor verbeteringen en innovaties. Om die reden wordt het project vorm gegeven rondom de ontwikkeling en bouw van een prototype elektrolyse systeem dat wordt geïntegreerd met de duurzame energievoorziening van H2Hub Twente. De ontwikkeling van elektrolyse systemen (maar ook toepassingen van waterstof) vraagt om expertise op alle opleidingsniveaus die nog weinig beschikbaar is. Door de energietransitie neemt de vraag naar deze expertise sterk toe. De kennisinstellingen zijn partner binnen de SPRONG “decentrale waterstof” en zij willen met dit project via praktijkgericht onderzoek expertise binnen de betrokken onderzoekgroepen verder opbouwen. Belangrijk hierin is het leerproces structuur en borging te geven waardoor dit kan doorwerken binnen het onderwijs richting studenten en bedrijfsmedewerkers. De resultaten van dit project worden gedeeld met het netwerk maar ook via bijeenkomsten van de topsector energie en lectorenplatform LEVE. De impact van dit project: expertiseopbouw voor realisatie van decentrale waterstofsystemen als stimulans voor regionale bedrijfsontwikkeling én energietransitie!
The specific objective of HyScaling is to achieve a 25-30% cost reduction for levelized cost of hydrogen. This cost reduction will be achieved in 2030 when the HyScaling innovations have been fully implemented. HyScaling develops novel hardware (such as stacks & cell components), low-cost manufacturing processes, optimized integrated system designs and advanced operating and control strategies. In addition to the goal of accelerating implementation of hydrogen to decarbonize energy-intensive industry, HyScaling is built around industrial partners who are aiming to build a business on the HyScaling innovations. These include novel components for electrolysers (from catalysts to membranes, from electrode architectures to novel coatings) as well as electrolyser stacks and systems for different applications. For some innovations (e.g. a coating from IonBond, an electrode design from Veco) the consortium aims at starting commercialisation before the end of the program. A unique characteristic of the HyScaling program is the orientation on Use Cases. In addition to partners representing the Dutch manufacturing industry, end-users and technology providers are partner in the consortium. This enables the consortium to develop the electrolyser technology specifically for different applications. In order to be able to come to an assessment of the market for electrolysers and components, the use cases also include decentralized energy systems.Projectpartners:Nouryon, Tejin, Danieli Corus, VDL, Hauzer, VECO, lonbond, Fluor, Frames, Magneto, VONK, Borit, Delft IMP, ZEF, MTSA, SALD, Dotx control, Hydron Energy, MX, Polymers, VSL, Fraunhofer IPT, TNO, TU Delft, TU Eindhoven, ISPT, FMC.
