The improvement of passive fire protection of storage vessels is a key factor to enhance safety among the LPG distribution chain. A thermal and mechanical model based on finite elements simulations was developed to assess the behaviour of full size tanks used for LPG storage and transportation in fire engulfment scenarios. The model was validated by experimental results. A specific analysis of the performance of four different reference coating materials was then carried out, also defining specific key performance indicators (KPIs) to assess design safety margins in near-miss simulations. The results confirmed the wide influence of coating application on the expected vessel time to failure due to fire engulfment. Aquite different performance of the alternative coating materialswas evidenced. General correlationswere developed among the vessel time to failure and the effective coating thickness in full engulfment scenarios, providing a preliminary assessment of the coating thickness required to prevent tank rupture for a given time lapse. The KPIs defined allowed the assessment of the available safety margins in the reference scenarios analyzed and of the robustness of thermal protection design.
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Deze publicatie is binnen het project 'nieuwe materialen' ontwikkeld en geeft informatie over het ontwerpen van dunne metaalplaat producten met diktes van 0,3 t/m ca. 3 mm, uitgaande van de Eindige Elementen Methode. In het kader van dit project zijn tevens uitgegeven: TI.04.18 'Hoge Sterkte Staal in dunne plaat en buis', TI.04.19 'Roestvast staal in dunne plaat en buis', TI.04.20 'Scheidingstechnieken voor dunne plaat en buis' en TI.04.21 'Aluminium in dunne plaat en buis'.
This study introduces a detailed method for analyzing the buckling behavior of laminated composite structures strengthened with multi-walled carbon nanotubes (MWCNTs). We propose a multi-scale analysis that combines analytical and computational techniques to assess the mechanical performance of MWCNT-reinforced composites under combined moisture, temperature, and mechanical stress conditions. The Halpin-Tsai equations are used to calculate the overall stiffness properties of the nano-enhanced matrix, considering factors like MWCNT clustering, alignment, and curvature. Additionally, we incorporate the nanoscopic, size-dependent features of MWCNTs into our model. The Chamis micromechanical formulas are applied to determine the individual elastic properties of the nanocomposite layers, considering the impacts of temperature and moisture. We then explore how variables such as MWCNT content and size, along with temperature and moisture levels, influence the critical buckling load of MWCNT-based laminated composite beams and plates using our multi-scale model. Our results are successfully compared with existing experimental and theoretical data to validate our approach. The developed method offers significant insights for the design and optimization of MWCNT-reinforced composites, potentially benefiting various engineering fields, including aerospace and automotive industries.
