Power-to-gas technologies are considered to be part of the future energy sys- tem, but their viability and applicability need to be assessed. Therefore, models for the viability of farm-scale bio-power-to-methane supply chains to produce green gas were analysed in terms of levelised cost of energy, energy efficiency and saving of greenhouse gas emission. In bio-power-to-methane, hydrogen from electrolysis driven by surplus renewable electricity and carbon dioxide from biogas are converted to methane by microbes in an ex situ trickle-bed reactor. Such bio-methanation could replace the current upgrading of biogas to green gas with membrane technology. Four scenarios were compared: a refer- ence scenario without bio-methanation (A), bio-methanation (B), bio-methanation combined with membrane upgrading (C) and the latter with use of renewable energy only (all-green; D). The reference scenario (A) has the lowest costs for green gas production, but the bio-methanation scenarios (B-D) have higher energy efficiencies and environmental benefits. The higher costs of the bio-methanation scenarios are largely due to electrolysis, whereas the environmental benefits are due to the use of renewable electricity. Only the all- green scenario (D) meets the 2026 EU goal of 80% reduction of greenhouse gas emissions, but it would require a CO2 price of 200 € t−1 to achieve the levelised cost of energy of 65 €ct Nm−3 of the reference scenario. Inclusion of the intermittency of renewable energy in the scenarios substantially increases the costs. Further greening of the bio-methanation supply chain and how intermittency is best taken into account need further investigation.
Excess of renewable electricity from wind turbines or solar panels is used for electrolysis of water. To store this renewable energy as methane, the hydrogen is fed to an anaerobic digester to stimulate biological methanation by hydrogenotrophic methanogens. These work packages focus on the best ways for hydrogen delivery and the community changes in a biomethanation reactor as a result of hydrogen supply.
In the course of the “energie transitie” hydrogen is likely to become a very important energy carrier. The production of hydrogen (and oxygen) by water electrolysis using electricity from sun or wind is the only sustainable option. Water electrolysis is a well-developed technique, however the production costs of hydrogen by electrolysis are still more expensive than the conventional (not sustainable) production by steam reforming. One challenge towards the large scale application of water electrolysis is the fabrication of stable and cheap (noble metal free) electrodes. In this project we propose to develop fabrication methods for working electrodes and membrane electrode stack (MEAs) that can be used to implement new (noble metal free) electrocatalysts in water electrolysers.
This Professional Doctorate (PD) research focuses on optimizing the intermittency of CO₂-free hydrogen production using Proton Exchange Membrane (PEM) and Anion Exchange Membrane (AEM) electrolysis. The project addresses challenges arising from fluctuating renewable energy inputs, which impact system efficiency, degradation, and overall cost-effectiveness. The study aims to develop innovative control strategies and system optimizations to mitigate efficiency losses and extend the electrolyzer lifespan. By integrating dynamic modeling, lab-scale testing at HAN University’s H2Lab, and real-world validation with industry partners (Fluidwell and HyET E-Trol), the project seeks to enhance electrolyzer performance under intermittent conditions. Key areas of investigation include minimizing start-up and shutdown losses, reducing degradation effects, and optimizing power allocation for improved economic viability. Beyond technological advancements, the research contributes to workforce development by integrating new knowledge into educational programs, bridging the gap between research, industry, and education. It supports the broader transition to a CO₂-free energy system by ensuring professionals are equipped with the necessary skills. Aligned with national and European sustainability goals, the project promotes decentralized hydrogen production and strengthens the link between academia and industry. Through a combination of theoretical modeling, experimental validation, and industrial collaboration, this research aims to lower the cost of green hydrogen and accelerate its large-scale adoption.
Surface Active Agents, or surfactants, are chemicals which provide a surface (interface) activity when dispersed in liquids. They have different purposes, can be used as herbicides, anti-foaming agents, adhesives, cleaning agents and softeners. For cleaning purposes, their function is to alter (decrease) liquid surface tension. In this function they are ubiquitous in both industrial processes (cleaning of production equipment, storage vats, packaging lines, and cooking units either during the manufacturing process) and domestic applications. ProtoNeat proposes an alternative way to decrease water surface tension without adding chemicals (surfactants). This can be done by charging the water (producing protonically charged water) [2], i.e. positive and negative Bjerrum-defect like charges [3, 4]. This phenomenon was experimentally observed by Fuchs et al [5] in anolyte and catholyte when doing high voltage electrolysis of highly pure water during the so-called ‘floating water bridge’ experiment. The work done by the authors, when working with this “bridge”, showed that, in case of positive excess charge, the hydronium ions migrate to the surface [8] thereby significantly lowering the surface tension [9,10]. However, for how long this effect can be maintained and how effective it is to produce such water is still unknown. ProtoNeat wants to tackle these two questions and investigate whether a continuous production of protonically charged water as an environmentally friendly and sustainable cleaning agent is possible.
