The intermittency of renewable energy technologies requires adequate storage technologies. Hydrogen systems consisting of electrolysers, storage tanks, and fuel cells can be implemented as well as batteries. The requirements of the hydrogen purification unit is missing from literature. We measured the same for a 4.5 kW PEM electrolyser to be 0.8 kW for 10 min.A simulation to hybridize the hydrogen system, including its purification unit, with lithium-ion batteries for energy storage is presented; the batteries also support the electrolyser. We simulated a scenario for operating a Dutch household off-electric-grid using solar and wind electricity to find the capacities and costs of the components of the system.Although the energy use of the purification unit is small, it influences the operation of the system, affecting the sizing of the components. The battery as a fast response efficient secondary storage system increases the ability of the electrolyser to start up.
Hydrogen (H2) is a key element in the Dutch energy transition, considered a sources of flexibility to balance the variable renewable energy sources, facilitating its integration into the energy system. But also as an energy carrier. Both the gas and electricity transmission operators (TSO) have the vision to interconnect their networks with H2, by distributing the green H2 produced with offshore electrolysers into high pressure gas pipelines to relive the overload electric network. The planned compressed H2 pipelines cross the north of North-Holland region, offering a backbone for a H2 economy. Furthermore, at regional level there are already a big number of privet-public H2 developments, among them the DuWaAl, which is a H2 production-demand chain, consists of 1) An H2 mill, 2) 5 filling stations in the region and 3) a large fleet of trucks and other users. Because of these developments, the North-Holland region needs a better insight into the position that H2 could fulfil in the local energy system to contribute to the energy transition. The aim of this research is to analyse these H2 economy, from the emergent to settled, by identifying early and potential producer- consumer, considering the future infrastructure requirements, and exploring economy-environmental impacts of different supply paths
This paper proposes a Hybrid Microgrid (HμG) model including distributed generation (DG) and a hydrogen-based storage system, controlled through a tailored control strategy. The HμG is composed of three DG units, two of them supplied by solar and wind sources, and the latter one based on the exploitation of theProton Exchange Membrane (PEM) technology. Furthermore, the system includes an alkaline electrolyser, which is used as a responsive load to balance the excess of Variable Renewable Energy Sources (VRES) production, and to produce the hydrogen that will be stored into the hydrogen tank and that will be used to supply the fuel cell in case of lack of generation. The main objectives of this work are to present a validated dynamic model for every component of the HμG and to provide a strategy to reduce as much as possible the power absorption from the grid by exploiting the VRES production. The alkaline electrolyser and PEM fuel cell models are validated through real measurements. The State of Charge (SoC) of the hydrogen tank is adjusted through an adaptive scheme. Furthermore, the designed supervisor power control allows reducing the power exchange and improving the system stability. Finally, a case, considering a summer load profile measured in an electrical substation of Politecnico di Torino, is presented. The results demonstrates the advantages of a hydrogen-based micro-grid, where the hydrogen is used as medium to store the energy produced by photovoltaic and wind systems, with the aim to improve the self-sufficiency of the system
MULTIFILE
In this proposal, a consortium of knowledge institutes (wo, hbo) and industry aims to carry out the chemical re/upcycling of polyamides and polyurethanes by means of an ammonolysis, a depolymerisation reaction using ammonia (NH3). The products obtained are then purified from impurities and by-products, and in the case of polyurethanes, the amines obtained are reused for resynthesis of the polymer. In the depolymerisation of polyamides, the purified amides are converted to the corresponding amines by (in situ) hydrogenation or a Hofmann rearrangement, thereby forming new sources of amine. Alternatively, the amides are hydrolysed toward the corresponding carboxylic acids and reused in the repolymerisation towards polyamides. The above cycles are particularly suitable for end-of-life plastic streams from sorting installations that are not suitable for mechanical/chemical recycling. Any loss of material is compensated for by synthesis of amines from (mixtures of) end-of-life plastics and biomass (organic waste streams) and from end-of-life polyesters (ammonolysis). The ammonia required for depolymerisation can be synthesised from green hydrogen (Haber-Bosch process).By closing carbon cycles (high carbon efficiency) and supplementing the amines needed for the chain from biomass and end-of-life plastics, a significant CO2 saving is achieved as well as reduction in material input and waste. The research will focus on a number of specific industrially relevant cases/chains and will result in economically, ecologically (including safety) and socially acceptable routes for recycling polyamides and polyurethanes. Commercialisation of the results obtained are foreseen by the companies involved (a.o. Teijin and Covestro). Furthermore, as our project will result in a wide variety of new and drop-in (di)amines from sustainable sources, it will increase the attractiveness to use these sustainable monomers for currently prepared and new polyamides and polyurethanes. Also other market applications (pharma, fine chemicals, coatings, electronics, etc.) are foreseen for the sustainable amines synthesized within our proposition.
Beproeven van emissiearme verwarmingssystemen in het HEAT House (onderdeel proeftuin van EnTranCe) welke ter vervanging van huidige HR cv-ketels kunnen worden ingezet en voorbereid zijn voor gebruik van biogas en waterstof.
In the course of the “energie transitie” hydrogen is likely to become a very important energy carrier. The production of hydrogen (and oxygen) by water electrolysis using electricity from sun or wind is the only sustainable option. Water electrolysis is a well-developed technique, however the production costs of hydrogen by electrolysis are still more expensive than the conventional (not sustainable) production by steam reforming. One challenge towards the large scale application of water electrolysis is the fabrication of stable and cheap (noble metal free) electrodes. In this project we propose to develop fabrication methods for working electrodes and membrane electrode stack (MEAs) that can be used to implement new (noble metal free) electrocatalysts in water electrolysers.
