Anthocyanins do not have a toxic effect, they are safe for humans, and they are of interest as natural dyes. They are used in the food industry, cosmetics, perfumery and medicine. Nowadays, the question of the use of anthocyanins in solar cells is being widely considered. Dye-sensitized solar cell (DSSC) has attracted much attention as a new promising solar to electric convertor because of its low production cost, easy fabrication, more environmental friendliness compared to silicon or perovskite solar cell.
The chromatographic behavior of petanin, petunidin-3-O-[6-O-(4-O-(E)-para-coumaroyl-O-α-rhamnopyranosyl)-β-glucopyranoside]-5-O-β-glucopyranoside, is studied for the first time under conditions of reversed-phase high performance liquid chromatography in mobile phases with different pH values. The relationship between chromatographic behavior (retention time and peak efficiency) and transitions between different forms of anthocyanins is discussed. Analysis of the data obtained in the 2 to 6.5 range of mobile pH phases, the absorption spectra of petanin, and the results from studying the effect of adding tetrabutylammonium bromide to the mobile phase shows that increasing the pH results in the formation of uncharged and anionic forms, in addition to the pseudobase form.
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