Excess of renewable electricity from wind turbines or solar panels is used for electrolysis of water. To store this renewable energy as methane, the hydrogen is fed to an anaerobic digester to stimulate biological methanation by hydrogenotrophic methanogens. This workpackage focusses on the best ways for hydrogen delivery and the community changes in a biomethanation reactor as a result of hydrogen supply.
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Excess of renewable electricity from wind turbines or solar panels is used for electrolysis of water. To store this renewable energy as methane, the hydrogen is fed to an anaerobic digester to stimulate biological methanation by hydrogenotrophic methanogens. These work packages focus on the best ways for hydrogen delivery and the community changes in a biomethanation reactor as a result of hydrogen supply.
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Ammonia is heavily used in agriculture as a fertilizer and in industry as a raw material for the production of various organic nitrogen compounds. Its high hydrogen content and its established infrastructure for both storage and distribution makes ammonia a prominent candidate for storing fluctuating renewable energy. The Haber-Bosch heterogenous reaction of hydrogen and nitrogen on an iron-based catalyst is used today at large scale ammonia production sites. The current industrial hydrogen production is dominated by fossil energy sources. The traditional Haber-Bosch process can become green and carbon-free if renewable electricity is used for hydrogen generation. However, a continuous operation of power to ammonia can be challenging with a fluctuating renewable energy source. Techno-economic models show that electrolysis and the hydrogen supply chain is the main dominating cost factor of power to ammonia.
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In the course of the “energie transitie” hydrogen is likely to become a very important energy carrier. The production of hydrogen (and oxygen) by water electrolysis using electricity from sun or wind is the only sustainable option. Water electrolysis is a well-developed technique, however the production costs of hydrogen by electrolysis are still more expensive than the conventional (not sustainable) production by steam reforming. One challenge towards the large scale application of water electrolysis is the fabrication of stable and cheap (noble metal free) electrodes. In this project we propose to develop fabrication methods for working electrodes and membrane electrode stack (MEAs) that can be used to implement new (noble metal free) electrocatalysts in water electrolysers.
The growing energy demand and environmental impact of traditional sources highlight the need for sustainable solutions. Hydrogen produced through water electrolysis, is a flexible and clean energy carrier capable of addressing large-electricity storage needs of the renewable but intermittent energy sources. Among various technologies, Proton Exchange Membrane Water Electrolysis (PEMWE) stands out for its efficiency and rapid response, making it ideal for grid stabilization. In its core, PEMWEs are composed of membrane electrode assemblies (MEA), which consist of a proton-conducting membrane sandwiched between two catalyst-coated electrodes, forming a single PEMWE cell unit. Despite the high efficiency and low emissions, a principal drawback of PEMWE is the capital cost due to high loading of precious metal catalysts and protective coatings. Traditional MEA catalyst coating methods are complex, inefficient, and costly to scale. To circumvent these challenges, VSParticle developed a technology for nanoparticle film production using spark ablation, which generates nanoparticles through high-voltage discharges between electrodes followed by an impaction printing module. However, the absence of liquids poses challenges, such as integrating polymeric solutions (e.g., Nafion®) for uniform, thicker catalyst coatings. Electrohydrodynamic atomization (EHDA) stands out as a promising technique thanks to its strong electric fields used to generate micro- and nanometric droplets with a narrow size distribution. Co-axial EHDA, a variation of this technique, utilizes two concentric needles to spray different fluids simultaneously.The ESPRESSO-NANO project combines co-axial EHDA with spark ablation to improve catalyst uniformity and performance at the nanometer scale by integrating electrosprayed ionomer nanoparticles with dry metal nanoparticles, ensuring better distribution of the catalyst within the nanoporous layer. This novel approach streamlines numerous steps in traditional synthesis and electrocatalyst film production which will address material waste and energy consumption, while simultaneously improve the electrochemical efficiency of PEMWEs, offering a sustainable solution to the global energy crisis.
Surface Active Agents, or surfactants, are chemicals which provide a surface (interface) activity when dispersed in liquids. They have different purposes, can be used as herbicides, anti-foaming agents, adhesives, cleaning agents and softeners. For cleaning purposes, their function is to alter (decrease) liquid surface tension. In this function they are ubiquitous in both industrial processes (cleaning of production equipment, storage vats, packaging lines, and cooking units either during the manufacturing process) and domestic applications. ProtoNeat proposes an alternative way to decrease water surface tension without adding chemicals (surfactants). This can be done by charging the water (producing protonically charged water) [2], i.e. positive and negative Bjerrum-defect like charges [3, 4]. This phenomenon was experimentally observed by Fuchs et al [5] in anolyte and catholyte when doing high voltage electrolysis of highly pure water during the so-called ‘floating water bridge’ experiment. The work done by the authors, when working with this “bridge”, showed that, in case of positive excess charge, the hydronium ions migrate to the surface [8] thereby significantly lowering the surface tension [9,10]. However, for how long this effect can be maintained and how effective it is to produce such water is still unknown. ProtoNeat wants to tackle these two questions and investigate whether a continuous production of protonically charged water as an environmentally friendly and sustainable cleaning agent is possible.
