Chain-extended starch is prepd. in that starch is polymd. in an aq. soln. at pH 6.0-8.3 by means of glucosyl fluoride in the presence of inorg. phosphate, sucrose phosphorylase, and potato phosphorylase. [on SciFinder(R)]
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Dit document bevat in grote lijnen de opzet van ZAP. Binnen Zernike Advanced Processing (ZAP) wordt de mogelijkheid gecreëerd voor het uitvoeren van opschalingsexperimenten op het gebied van bioprocestechnologie en groene chemie.
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In mijn vorige blog schreef ik dat ik "groene chemie" niet zo'n goede term vind. Dit bericht borduurt daar enigszins op voort en is mijn persoonlijke kritische noot bij de transitie naar een groene(re) economie die momenteel in volle gang is.
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A process for the prepn. of arom. compds. from a feed stream contg. biomass or mixts. of biomass, the process comprising: a) subjecting a feed stream contg. biomass or mixts. of biomass to a process to afford a conversion product comprising arom. compds.; b) recovering the arom. compds. from said conversion product; c) sepg. a higher mol. wt. fraction comprising polyarom. hydrocarbons (PAH) from a lower mol. wt. fraction comprising benzene, toluene and xylene (BTX) by distn.; d) reducing at least part of said higher mol. wt. fraction to obtain a reduced fraction comprising polycyclic aliphatics (PCA); and e) subjecting the higher mol. wt. fraction obtained in step c), the reduced fraction obtained in step d), or a mixt. thereof, to a process to obtain lower mol. wt. aroms. (BTX). [on SciFinder(R)]
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Bio-aromatics (benzene, toluene, xylenes, BTX) were prepared by the catalytic pyrolysis of six different black liquors using both in situ and ex situ approaches. A wide range of catalysts was screened and conditions were optimized in microscale reactors. Up to 7 wt % of BTX, based on the organic fraction of the black liquors, was obtained for both the in situ and ex situ pyrolysis ( T = 500-600 °C) using a Ga-modified H-ZSM-5 catalyst. The in situ catalytic pyrolysis of black liquors from hardwood paper mills afforded slightly higher yields of aromatics/BTX than softwood black liquors, a trend that could be confirmed by the results obtained in the ex situ catalytic pyrolysis. An almost full deoxygenation of the lignin and carbohydrate fraction was achieved and both organic fractions were converted to a broad range of (substituted) aromatics. The zeolite catalyst used was remarkably stable and even after 100 experiments in batch mode with intermittent oxidative catalyst regeneration, the yields and selectivity toward BTX remained similar. The ex situ pyrolysis of black liquor has potential for large-scale implementation in a paper mill without disturbing the paper production process.
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A series of new, easily synthesized C60-fullerene derivatives is introduced that allow for optimization of the interactions between rr-P3HT and the fullerene by systematic variation of the size of the ester group. Two compounds gave overall cell efficiencies of 4.8%, clearly outperforming [60]PCBM which gives 4.3% under identical conditions.
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In recent years, the number of publications on innovation in the construction industry has increased. Many of these documents address qualitative issues, e.g. policies for innovation and present case studies. A more quantitative approach is taken in this paper, which is the continuation of a previous study. It focuses on main types and sources of innovation in the construction industry, and includes an analysis of 55 years of publications in two leading Dutch professional journals. The results show a recent increase in innovation, with two-thirds of innovations coming out of supplying industries. Construction companies contribute mainly in process innovations. Innovation in construction remains to be technology- rather than market-driven. Regulations have a surprising impact, as over one-third of all counted new innovations are related to new regulations.
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The 'AgroCycle' project investigates whether a cooperation of farms can become self-sufficient in energy and fertilization by using manure and organic waste streams for the production of energy, green fuel and green fertilizers by means of anaerobic digestion (AD). In the project, the project partners aim to link the nutrient cycle (from manure to digestate to green fertilizer) to a self-sufficient energy system (biomass to biogas to green fuel for processing the land) through the combined production of biogas and green fertilizers. The financial feasibility of a bio-digester is highly dependent on the use and economic value of the digestate. This combined approach increases both feasibility and sustainability (environmental impacts and CO2 emissions). To explore the feasibility of the aforementioned concept, use is made of the existing 'BioGas simulator' model developed by Hanze UAS to simulate the technical process of decentralized production of biogas and the economic cost.
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Ageing-in-place is the preferred way of living for older individuals in an ageing society. It can be facilitated through architectural and technological solutions in the home environment. Dementia poses additional challenges when designing, constructing, or retrofitting housing facilities that support ageing-in-place. Older adults with dementia and their partners ask for living environments that support independence, compensate for declining and vitality, and lower the burden of family care. This study reports the design process of a demonstration home for people with dementia through performing a literature review and focus group sessions. This design incorporates modifications in terms of architecture, interior design, the indoor environment, and technological solutions. Current design guidelines are frequently based on small-scale studies, and, therefore, more systematic field research should be performed to provide further evidence for the efficacy of solutions. The dwellings of people with dementia are used to investigate the many aspects of supportive living environments for older adults with dementia and as educational and training settings for professionals from the fields of nursing, construction, and building services engineering.
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The project BioP2M came to a close in June 2019 after a consortium of stakeholders in the field of energy transition worked together to research the diverse role of Methane. In this report the results are presented and future plans are discussed.
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