Prophylactic replacement therapy is the cornerstone of treatment in severe haemophilia. Regular infusions with clotting factor concentrate have been proven effective to prevent bleeding, subsequent (joint) damage, and positively affect the impact of haemophilia on daily life [1]. Patients or parents of younger patients learn to infuse clotting factor concentrate in a peripheral vein (i.v.) or a central venous access device (CVAD) [2].
The scope of this thesis of Gerrit Bouwhuis, lecturer at Saxion Research Centre for Design and Technology in Enschede is the development of a new industrial applicable pre-treatment process for cotton based on catalysis. The pre-treatment generally consists of desizing, scouring and bleaching. These processes can be continuous or batch wise. Advances in the science of biocatalytic pre-treatment of cotton and catalytic bleaching formed the scientific basis for this work. The work of Agrawal on enzymes for bio-scouring and of Topalovic on catalytic bleaching led to the conclusion that reduced reaction temperatures for the pre-treatment processes of cotton are possible. A second reason for the present work is a persistent and strong pressure on the industry to implement ‘more sustainable’ and environmental friendlier processes. It was clear that for the industrial implementation of the newly developed process it would be necessary to ‘translate’ the academic knowledge based on the catalysts, into a process at conditions that are applicable in textile industry. Previous experiences learned that the transition from academic knowledge into industrial applicable processes often failed. This is caused by lack of experience of university researchers with industrial product and process development as well as a lack of awareness of industrial developers of academic research. This is especially evident for the so-called Small and Medium Enterprises (SME’s). To overcome this gap a first step was to organize collaboration between academic institutes and industries. The basis for the collaboration was the prospect of this work for benefits for all parties involved. A rational approach has been adopted by first gathering knowledge about the properties and morphology of cotton and the know how on the conventional pre-treatment process. To be able to understand the conventional processes it was necessary not only to explore the chemical and physical aspects but also to evaluate the process conditions and equipment that are used. This information has been the basis for the present lab research on combined bio-catalytic desizing and scouring as well as catalytic bleaching. For the measurement of the performance of the treatments and the process steps, the performance indicators have been evaluated and selected. Here the choice has been made to use industrially known and accepted performance indicators. For the new bio-catalytic pre-treatment an enzyme cocktail, consisting of amylase, cutinase and pectinase has been developed. The process conditions in the enzyme cocktail tests have been explored reflecting different pre-treatment equipment as they are used in practice and for their different operation conditions. The exploration showed that combined bio-catalytic desizing and scouring seemed attractive for industrial application, with major reduction of the reaction and the rinsing temperatures, leading to several advantages. The performance of this treatment, when compared with the existing industrial treatment showed that the quality of the treated fabric was comparable or better than the present industrial standard, while concentrations enzymes in the cocktail have not yet been fully optimized. To explore the application of a manganese catalyst in the bleaching step of the pre-treatment process the fabrics were treated with the enzyme cocktail prior to the bleaching. It has been decided not to use conventional pre-treatment processes because in that case the combined desizing and scouring step would not be integrated in the newly developed process. To explore catalytic bleaching it has been tried to mimic the existing industrial processes where possible. The use of the catalyst at 100°C, as occurs in a conventional steamer, leads to decomposition of the catalyst and thus no bleach activation occurs. This led to the conclusion that catalytic bleaching is not possible in present steamers nor at low temperatur
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Synthetic fibers, mainly polyethylene terephthalate (PET), polyamide (PA), polyacrylonitrile (PAN) and polypropylene (PP), are the most widely used polymers in the textile industry. These fibers surpass the production of natural fibers with a market share of 54.4%. The advantages of these fibers are their high modulus and strength, stiffness, stretch or elasticity, wrinkle and abrasion resistances, relatively low cost, convenient processing, tailorable performance and easy recycling. The downside to synthetic fibers use are reduced wearing comfort, build-up of electrostatic charge, the tendency to pill, difficulties in finishing, poor soil release properties and low dyeability. These disadvantages are largely associated with their hydrophobic nature. To render their surfaces hydrophilic, various physical, chemical and bulk modification methods are employed to mimic the advantageous properties of their natural counterparts. This review is focused on the application of recent methods for the modification of synthetic textiles using physical methods (corona discharge, plasma, laser, electron beam and neutron irradiations), chemical methods (ozone-gas treatment, supercritical carbon dioxide technique, vapor deposition, surface grafting, enzymatic modification, sol-gel technique, layer-by-layer deposition of nano-materials, micro-encapsulation method and treatment with different reagents) and bulk modification methods by blending polymers with different compounds in extrusion to absorb different colorants. Nowadays, the bulk and surface functionalization of synthetic fibers for various applications is considered as one of the best methods for modern textile finishing processes (Tomasino, 1992). This last stage of textile processing has employed new routes to demonstrate the great potential of nano-science and technology for this industry (Lewin, 2007). Combination of physical technologies and nano-science enhances the durability of textile materials against washing, ultraviolet radiation, friction, abrasion, tension and fading (Kirk–Othmer, 1998). European methods for application of new functional finishing materials must meet high ethical demands for environmental-friendly processing (Fourne, 1999). For this purpose the process of textile finishing is optimized by different researchers in new findings (Elices & Llorca, 2002). Application of inorganic and organic nano-particles have enhanced synthetic fibers attributes, such as softness, durability, breathability, water repellency, fire retardancy and antimicrobial properties (Franz, 2003; McIntyre, 2005; Xanthos, 2005). This review article gives an application overview of various physical and chemical methods of inorganic and organic structured material as potential modifying agents of textiles with emphasis on dyeability enhancements. The composition of synthetic fibers includes polypropylene (PP), polyethylene terephthalate (PET), polyamides (PA) or polyacrylonitrile (PAN). Synthetic fibers already hold a 54% market share in the fiber market. Of this market share, PET alone accounts for almost 50% of all fiber materials in 2008 (Gubitz & Cavaco-Paulo, 2008). Polypropylene, a major component for the nonwovens market accounts for 10% of the market share of both natural and synthetic fibers worldwide (INDA, 2008 and Aizenshtein, 2008). It is apparent that synthetic polymers have unique properties, such as high uniformity, mechanical strength and resistance to chemicals or abrasion. However, high hydrophobicity, the build-up of static charges, poor breathability, and resistant to finishing are undesirable properties of synthetic materials (Gubitz & Cavaco-Paulo, 2008). Synthetic textile fibers typically undergo a variety of pre-treatments before dyeing and printing is feasible. Compared to their cotton counterparts, fabrics made from synthetic fibers undergo mild scouring before dyeing. Nonetheless, these treatments still create undesirable process conditions wh
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Climate change is one of the most critical global challenges nowadays. Increasing atmospheric CO2 concentration brought by anthropogenic emissions has been recognized as the primary driver of global warming. Therefore, currently, there is a strong demand within the chemical and chemical technology industry for systems that can covert, capture and reuse/recover CO2. Few examples can be seen in the literature: Hamelers et al (2013) presented systems that can use CO2 aqueous solutions to produce energy using electrochemical cells with porous electrodes; Legrand et al (2018) has proven that CDI can be used to capture CO2 without solvents; Shu et al (2020) have used electrochemical systems to desorb (recover) CO2 from an alkaline absorbent with low energy demand. Even though many efforts have been done, there is still demand for efficient and market-ready systems, especially related to solvent-free CO2 capturing systems. This project intends to assess a relatively efficient technology, with low-energy costs which can change the CO2 capturing market. This technology is called whorlpipe. The whorlpipe, developed by Viktor Schauberger, has shown already promising results in reducing the energy and CO2 emissions for water pumping. Recently, studies conducted by Wetsus and NHL Stenden (under submission), in combination with different companies (also members in this proposal) have shown that vortices like systems, like the Schauberger funnel, and thus “whorlpipe”, can be fluid dynamically represented using Taylor-Couette flows. This means that such systems have a strong tendency to form vortices like fluid-patterns close to their air-water interface. Such flow system drastically increase advection. Combined with their higher area to volume ratio, which increases diffusion, these systems can greatly enhance gas capturing (in liquids), and are, thus, a unique opportunity for CO2 uptake from the air, i.e. competing with systems like conventional scrubbers or bubble-based aeration.
Als gevolg van de energietransitie wordt het steeds moeilijker om energieaanbod en -vraag op elkaar af te stemmen en ontstaan problemen op het elektriciteitsnet. Energieopslag biedt een oplossing: duurzame energie wordt opgeslagen op momenten dat er aanbod en weinig energievraag is en beschikbaar gesteld wanneer er weinig aanbod en veel vraag is. Lokale opslag biedt een kans om lokale uitval van het elektriciteitsnet te voorkomen en geeft meerwaarde aan duurzame energie. Opslag in waterstof is uitermate geschikt voor zowel toepassingen op MW-schaal (windparken), voor seizoensopslag en voor toepassingen waar distributie relevant is. De wens van bedrijventerreinen om te verduurzamen biedt een kans om gericht aan oplossingen voor lokale energieopslag in waterstof en bijbehorende toepassingen te werken. In dit project werkt de HAN samen met MKB-bedrijven, Saxion, TU Delft, lokale overheden en een aantal overige partners aan het ontwikkelen en optimaliseren van een energieopslagsysteem gebaseerd op waterstof en bijbehorende waterstoftoepassingen op en voor bedrijventerrein IPKW in Arnhem. Beschikbare windenergie van in aanbouw zijnde turbines langs de Rijn bij IPKW vormen de aanleiding voor het ontwerpen, modelleren, construeren en testen van een (geschaald) energieopslagsysteem gebaseerd op de productie, en opslag van waterstof. Specifieke toepassingen op het industriepark worden geïnventariseerd, en waar mogelijk gerealiseerd en gemonitord, voor met name lokaal bedrijfstransport en elektriciteitslevering. Scenario’s voor ontwikkeling en toepassing van de technologie ontwikkeld en haalbaarheidsstudies uitgevoerd. Kennis en expertise worden ontwikkeld om het proces van optimale implementatie van waterstof voor energieopslag in een energieketen met specifieke toepassingen op een bedrijventerrein te ondersteunen. Met dit project bouwen wij voort op de vele eerdere waterstofprojecten die bij de HAN zijn uitgevoerd en maken we gebruik van ons recent gerealiseerde shared facility HAN Waterstoflab op IPKW.
Belangrijke uitdagingen binnen de energietransitie zijn de beschikbaarheid van waterstof uit duurzame energiebronnen als alternatief voor fossiele brandstoffen en het voorkomen van congestie op het elektriciteitsnet door toenemende vraag naar en aanbod van elektriciteit. Decentrale productie, opslag en toepassing van waterstof biedt voor beide uitdagingen een oplossing, maar om dit te realiseren zijn innovaties en kennisontwikkeling nodig. In dit RAAK MKB project willen bedrijven en kennisinstellingen als partners van het groeiende netwerk rondom waterstof innovatiecentrum H2Hub Twente, expertise ontwikkelen voor realisatie van decentrale elektrolyse systemen. De betrokken bedrijven zijn zich aan het ontwikkelen om systeemoplossingen voor de markt van decentrale elektrolyse aan te kunnen bieden, maar hebben nog stappen te maken in de benodigde expertise hiervoor. De kloof die de bedrijven in dit project willen overbruggen: van theoretisch inzicht en expertise op deelaspecten naar expertise om goed werkende systemen te kunnen realiseren en begrip krijgen van mogelijkheden voor verbeteringen en innovaties. Om die reden wordt het project vorm gegeven rondom de ontwikkeling en bouw van een prototype elektrolyse systeem dat wordt geïntegreerd met de duurzame energievoorziening van H2Hub Twente. De ontwikkeling van elektrolyse systemen (maar ook toepassingen van waterstof) vraagt om expertise op alle opleidingsniveaus die nog weinig beschikbaar is. Door de energietransitie neemt de vraag naar deze expertise sterk toe. De kennisinstellingen zijn partner binnen de SPRONG “decentrale waterstof” en zij willen met dit project via praktijkgericht onderzoek expertise binnen de betrokken onderzoekgroepen verder opbouwen. Belangrijk hierin is het leerproces structuur en borging te geven waardoor dit kan doorwerken binnen het onderwijs richting studenten en bedrijfsmedewerkers. De resultaten van dit project worden gedeeld met het netwerk maar ook via bijeenkomsten van de topsector energie en lectorenplatform LEVE. De impact van dit project: expertiseopbouw voor realisatie van decentrale waterstofsystemen als stimulans voor regionale bedrijfsontwikkeling én energietransitie!
